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Handsome Jack from Borderlands 2 is hilarius, his comments between fights and after some missions are normally jokes so bad that they are good.

My call would be Solid Snake from Metal Gear because even though will take down any threats to his safety and freedom, he tries to see things from their perspective and a lot of times he honors the enemies he has killed. He also has knack of saying the right thing at the right time to defuse a situation or encourage someone (eg: Raiden when he wanted to kill himself in Meta Gear Solid 4, it was Solid's words which gave him the will to live on.)

Conker. All you have to do is play Conker's Bad Fur day for all of 5 minutes and his cynicism and sarcastic nature will show in spades.